基于MEA-BEA-DEEA三元胺体系的固体酸碱催化剂对CO2吸收解吸性能影响
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TQ 413

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上海市科委地方能力建设项目(23010503500)


Effect of solid acid-base catalyst based on MEA-BEA-DEEA ternary amine system on CO2 absorption and desorption performance
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    摘要:

    在热水减碳连续运行装置中,选取乙醇胺(monoethanolamine, MEA)、2-(丁基氨基)乙醇(2-butylaminoethanol, BEA)和二乙氨基乙醇(diethylaminoethanol, DEEA)作为吸收剂,研究三者按特定配比与不同催化剂组合后的CO2吸收与解吸性能,旨在获得该体系捕集CO2的最优方案,降低解吸能耗。实验结果表明:浓度为4.5 mol/L的MEA-BEA-DEEA三元胺体系,其CO2吸收、解吸性能均优于传统MEA质量分数30%的溶液的;当吸收塔进口温度为25 ℃且加入150 g HND-8催化剂时,该固体酸催化效果最优,此时循环容量为46.3 mmol CO2/min,解吸能耗为2.21 GJ/t CO2;在此基础上继续加入30 g白云石后,体系综合性能达到最佳,循环容量提升至53.8 mmol CO2/min,解吸能耗降至1.92 GJ/t CO2,解吸能耗与含MEA质量分数30%的溶液相比降低54.3%。

    Abstract:

    Monoethanolamine (MEA), 2-butylaminoethanol (BEA) and diethylaminoethanol (DEEA) were employed as absorbents in a continuous hot-water decarbonization apparatus to investigate the CO2 absorption and desorption performances of the three absorbents under specific proportions and different catalyst combinations, aiming to determine the optimal CO2 capture strategy and reduce desorption energy consumption. The experimental results show that the CO2 absorption and desorption performance of the 4.5 mol/L MEA-BEA-DEEA ternary amine system is superior to that of the traditional 30% (mass fraction) MEA solution. When the inlet temperature of the absorption tower is 25 ℃ and 150 g of HND-8 catalyst is added, the catalytic effect of solid acid is the best. At this time, the cyclic capacity is 46.3 mmol CO2/min and the desorption energy consumption is 2.21 GJ/t CO2. After adding another 30 g of dolomite on this basis, the overall performance of the system reached its peak, with the cyclic capacity increase to 53.8 mmol CO2/min and the desorption energy consumption reduce to 1.92 GJ/t CO2, representing a 54.3% reduction in desorption energy consumption relative to the 30% MEA solution.

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罗阳方,金晶,史焕聪,李煜.基于MEA-BEA-DEEA三元胺体系的固体酸碱催化剂对CO2吸收解吸性能影响[J].上海理工大学学报,2026,48(3):326-334.

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  • 收稿日期:2025-03-03
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  • 在线发布日期: 2026-06-30
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