SUS430连接体表面Mn-Co涂层制备过程热转化工艺优化
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TG 174.4

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国家自然科学基金资助项目(21706159)


Optimization of the thermal conversion process for Mn-Co coatings prepared on the surface of SUS430 interconnects
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    摘要:

    针对固体氧化物燃料电池(solid oxide fuel cell,SOFC)用SUS430连接体的高温氧化问题,采用电泳沉积技术制备了Mn-Co尖晶石涂层,系统优化了热处理温度、保温时间、升温速率和气氛等关键工艺参数。实验结果表明,优化的两步热转化工艺(1050 ℃、N2气氛保温2 h后,以2 ℃/min的升温速率升温至825 ℃,并在空气中保温2 h)可制备出性能优异的涂层。该涂层表现出显著的抗氧化性能,400 h高温氧化实验后,其氧化速率常数kp(2.4414×10–12 g2·cm?4·s?1)较空白试样降低1个数量级;同时,Mn-Co尖晶石涂层中Cr含量(质量分数为7.06%)较空白试样(质量分数为44.92%)明显降低,有效抑制了Cr的挥发和扩散。

    Abstract:

    To address the high-temperature oxidation issue of SUS430 interconnects for solid oxide fuel cell (SOFC), the electrophoretic deposition to fabricate an Mn-Co spinel coating was employed, and key process parameters including annealing temperature, holding time, heating rate, and atmosphere were optimized. The experimental results demonstrate that the optimized two-step thermal conversion process (holding for 2 h at 1 050 ℃ in N2 atmosphere, followed by heating at 2 ℃/min to 825 ℃ and holding for 2 h in air) yields a high-performance coating. The coating exhibits remarkable oxidation resistance, with an oxidation rate constant (2.4414×10–12 g2·cm?4·s?1) which is one order of magnitude lower than that of the blank specimen after 400 h high-temperature oxidation. Furthermore, the Mn-Co spinel coating has a Cr content (mass fraction of 7.06%) significantly lower than that in the blank specimen (mass fraction of 44.92%). This coating can effectively suppress the volatilization and diffusion of Cr.

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陶彦君,梁四凯,王文琼,徐成杰,王志远. SUS430连接体表面Mn-Co涂层制备过程热转化工艺优化[J].上海理工大学学报,2026,48(4):471-483.

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  • 收稿日期:2025-04-29
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  • 在线发布日期: 2026-09-15
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